Crystal structure of bis­{S-octyl-3-[(thio­phen-2-yl)methyl­idene]di­thio­carbazato-κ(2) N (3),S}nickel(II)

In the title complex, [Ni(C(14)H(21)N(2)S(3))(2)], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms...

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Detalles Bibliográficos
Autores principales: Khan, Sultana Shakila, Howlader, Md. Belayet Hossain, Sheikh, Md. Chanmiya, Miyatake, Ryuta, Zangrando, Ennio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439407/
https://www.ncbi.nlm.nih.gov/pubmed/37601399
http://dx.doi.org/10.1107/S2056989023005935
Descripción
Sumario:In the title complex, [Ni(C(14)H(21)N(2)S(3))(2)], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The mol­ecules stack at a distance of 3.623 (2) Å along the b-axis direction.

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