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Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2) N (3),S}nickel(II)
In the title complex, [Ni(C(14)H(21)N(2)S(3))(2)], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439407/ https://www.ncbi.nlm.nih.gov/pubmed/37601399 http://dx.doi.org/10.1107/S2056989023005935 |
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| author | Khan, Sultana Shakila Howlader, Md. Belayet Hossain Sheikh, Md. Chanmiya Miyatake, Ryuta Zangrando, Ennio |
| author_facet | Khan, Sultana Shakila Howlader, Md. Belayet Hossain Sheikh, Md. Chanmiya Miyatake, Ryuta Zangrando, Ennio |
| author_sort | Khan, Sultana Shakila |
| collection | PubMed |
| description | In the title complex, [Ni(C(14)H(21)N(2)S(3))(2)], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction. |
| format | Online Article Text |
| id | pubmed-10439407 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-104394072023-08-20 Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2) N (3),S}nickel(II) Khan, Sultana Shakila Howlader, Md. Belayet Hossain Sheikh, Md. Chanmiya Miyatake, Ryuta Zangrando, Ennio Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [Ni(C(14)H(21)N(2)S(3))(2)], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction. International Union of Crystallography 2023-07-11 /pmc/articles/PMC10439407/ /pubmed/37601399 http://dx.doi.org/10.1107/S2056989023005935 Text en © Khan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Khan, Sultana Shakila Howlader, Md. Belayet Hossain Sheikh, Md. Chanmiya Miyatake, Ryuta Zangrando, Ennio Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2) N (3),S}nickel(II) |
| title | Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
N
(3),S}nickel(II) |
| title_full | Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
N
(3),S}nickel(II) |
| title_fullStr | Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
N
(3),S}nickel(II) |
| title_full_unstemmed | Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
N
(3),S}nickel(II) |
| title_short | Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
N
(3),S}nickel(II) |
| title_sort | crystal structure of bis{s-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ(2)
n
(3),s}nickel(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439407/ https://www.ncbi.nlm.nih.gov/pubmed/37601399 http://dx.doi.org/10.1107/S2056989023005935 |
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