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Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide
In the title compound, C(25)H(17)N(3)O(5)S(2), intramolecular π–π interactions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C—H⋯O and C—H⋯N hydrogen bonds, forming layers pa...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439414/ https://www.ncbi.nlm.nih.gov/pubmed/37601397 http://dx.doi.org/10.1107/S2056989023006254 |
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| author | Mammadova, Gunay Z. Yakovleva, Elizaveta D. Burkin, Gleb M. Khrustalev, Victor N. Akkurt, Mehmet Çelikesir, Sevim Türktekin Bhattarai, Ajaya |
| author_facet | Mammadova, Gunay Z. Yakovleva, Elizaveta D. Burkin, Gleb M. Khrustalev, Victor N. Akkurt, Mehmet Çelikesir, Sevim Türktekin Bhattarai, Ajaya |
| author_sort | Mammadova, Gunay Z. |
| collection | PubMed |
| description | In the title compound, C(25)H(17)N(3)O(5)S(2), intramolecular π–π interactions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C—H⋯O and C—H⋯N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C—H⋯π interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H⋯H (30.2%), N⋯H/H⋯N (22.3%), C⋯H/H⋯C (17.9%) and O⋯H/H⋯O (15.4%) interactions make the most significant contributions to the crystal packing. |
| format | Online Article Text |
| id | pubmed-10439414 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-104394142023-08-20 Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide Mammadova, Gunay Z. Yakovleva, Elizaveta D. Burkin, Gleb M. Khrustalev, Victor N. Akkurt, Mehmet Çelikesir, Sevim Türktekin Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(25)H(17)N(3)O(5)S(2), intramolecular π–π interactions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C—H⋯O and C—H⋯N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C—H⋯π interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H⋯H (30.2%), N⋯H/H⋯N (22.3%), C⋯H/H⋯C (17.9%) and O⋯H/H⋯O (15.4%) interactions make the most significant contributions to the crystal packing. International Union of Crystallography 2023-07-21 /pmc/articles/PMC10439414/ /pubmed/37601397 http://dx.doi.org/10.1107/S2056989023006254 Text en © Mammadova et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Mammadova, Gunay Z. Yakovleva, Elizaveta D. Burkin, Gleb M. Khrustalev, Victor N. Akkurt, Mehmet Çelikesir, Sevim Türktekin Bhattarai, Ajaya Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title | Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title_full | Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title_short | Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| title_sort | crystal structure and hirshfeld surface analysis of 4-cyano-n-[(4-cyanophenyl)sulfonyl]-n-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439414/ https://www.ncbi.nlm.nih.gov/pubmed/37601397 http://dx.doi.org/10.1107/S2056989023006254 |
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