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Crystal structure and Hirshfeld surface analysis of bis­{(Z)-N′-[(E)-(furan-2-yl)methyl­idene]carbamo­hydrazono­thio­ato}nickel(II) methanol disolvate

In the title complex, [Ni(C(6)H(6)N(3)OS)(2)]·2CH(3)OH, the Ni(II) atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methyl­idene]carbamohydrazono­thioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni(II) are also connected by C—H⋯S inter­act...

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Detalles Bibliográficos
Autores principales: Azizova, Asmet N., Mammadova, Gunay Z., Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439423/
https://www.ncbi.nlm.nih.gov/pubmed/37601570
http://dx.doi.org/10.1107/S2056989023005182
Descripción
Sumario:In the title complex, [Ni(C(6)H(6)N(3)OS)(2)]·2CH(3)OH, the Ni(II) atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methyl­idene]carbamohydrazono­thioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni(II) are also connected by C—H⋯S inter­actions, while the H atoms of the NH(2) group of the ligands form R (4) (4)(8) motifs with the O atoms of the solvent ethyl alcohol mol­ecules. At the same time, the OH groups of the solvent ethyl alcohol mol­ecules form parallel layers to the (011) plane by the O—H⋯N inter­actions with the ligand N atom that is not bonded to the Ni(II) atom.. The layers are connected by van der Waals inter­actions. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (37.7%), C⋯H/H⋯C (14.6%), O⋯H/H⋯O (11.5%) and S⋯H/H⋯S (10.6%).