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Crystal structure and Hirshfeld surface analysis of bis{(Z)-N′-[(E)-(furan-2-yl)methylidene]carbamohydrazonothioato}nickel(II) methanol disolvate
In the title complex, [Ni(C(6)H(6)N(3)OS)(2)]·2CH(3)OH, the Ni(II) atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methylidene]carbamohydrazonothioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni(II) are also connected by C—H⋯S interact...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439423/ https://www.ncbi.nlm.nih.gov/pubmed/37601570 http://dx.doi.org/10.1107/S2056989023005182 |
Sumario: | In the title complex, [Ni(C(6)H(6)N(3)OS)(2)]·2CH(3)OH, the Ni(II) atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methylidene]carbamohydrazonothioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni(II) are also connected by C—H⋯S interactions, while the H atoms of the NH(2) group of the ligands form R (4) (4)(8) motifs with the O atoms of the solvent ethyl alcohol molecules. At the same time, the OH groups of the solvent ethyl alcohol molecules form parallel layers to the (011) plane by the O—H⋯N interactions with the ligand N atom that is not bonded to the Ni(II) atom.. The layers are connected by van der Waals interactions. A Hirshfeld surface analysis indicates that the most important contacts are H⋯H (37.7%), C⋯H/H⋯C (14.6%), O⋯H/H⋯O (11.5%) and S⋯H/H⋯S (10.6%). |
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