Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)

The title copper(II) complex, [Cu(C(16)H(13)NO(4))(C(3)H(4)N(2))], consists of a tridentate ligand synthesized from l-tyrosine and salicyl­aldehyde. One imidazole mol­ecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. The H...

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Detalles Bibliográficos
Autores principales: Suzuki, Soma, Akiyama, Yukihito, Nakane, Daisuke, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439432/
https://www.ncbi.nlm.nih.gov/pubmed/37601577
http://dx.doi.org/10.1107/S2056989023004735
Descripción
Sumario:The title copper(II) complex, [Cu(C(16)H(13)NO(4))(C(3)H(4)N(2))], consists of a tridentate ligand synthesized from l-tyrosine and salicyl­aldehyde. One imidazole mol­ecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (37.9%), C⋯H (28.2%) and O⋯H/H⋯O (21.2%) contacts.

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