Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)

The title copper(II) complex, [Cu(C(16)H(13)NO(4))(C(3)H(4)N(2))], consists of a tridentate ligand synthesized from l-tyrosine and salicyl­aldehyde. One imidazole mol­ecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. The H...

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Detalles Bibliográficos
Autores principales: Suzuki, Soma, Akiyama, Yukihito, Nakane, Daisuke, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439432/
https://www.ncbi.nlm.nih.gov/pubmed/37601577
http://dx.doi.org/10.1107/S2056989023004735
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author Suzuki, Soma
Akiyama, Yukihito
Nakane, Daisuke
Akitsu, Takashiro
author_facet Suzuki, Soma
Akiyama, Yukihito
Nakane, Daisuke
Akitsu, Takashiro
author_sort Suzuki, Soma
collection PubMed
description The title copper(II) complex, [Cu(C(16)H(13)NO(4))(C(3)H(4)N(2))], consists of a tridentate ligand synthesized from l-tyrosine and salicyl­aldehyde. One imidazole mol­ecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (37.9%), C⋯H (28.2%) and O⋯H/H⋯O (21.2%) contacts.
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spelling pubmed-104394322023-08-20 Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II) Suzuki, Soma Akiyama, Yukihito Nakane, Daisuke Akitsu, Takashiro Acta Crystallogr E Crystallogr Commun Research Communications The title copper(II) complex, [Cu(C(16)H(13)NO(4))(C(3)H(4)N(2))], consists of a tridentate ligand synthesized from l-tyrosine and salicyl­aldehyde. One imidazole mol­ecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (37.9%), C⋯H (28.2%) and O⋯H/H⋯O (21.2%) contacts. International Union of Crystallography 2023-06-02 /pmc/articles/PMC10439432/ /pubmed/37601577 http://dx.doi.org/10.1107/S2056989023004735 Text en © Suzuki et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Suzuki, Soma
Akiyama, Yukihito
Nakane, Daisuke
Akitsu, Takashiro
Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title_full Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title_short Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN (3))[N-(2-oxido­benzyl­idene)tyrosinato-κ(3) O,N,O′]copper(II)
title_sort crystal structure and hirshfeld surface analysis of (1h-imidazole-κn (3))[n-(2-oxido­benzyl­idene)tyrosinato-κ(3) o,n,o′]copper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439432/
https://www.ncbi.nlm.nih.gov/pubmed/37601577
http://dx.doi.org/10.1107/S2056989023004735
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