Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds

Single crystals of Ag(3)Dy(2)(NO(3))(9) (tris­ilver didysprosium nona­nitrate) were obtained from a mixture of AgNO(3) and Dy(NO(3))(3)·5 H(2)O. The new compound crystallizes in space group P4(1)32 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å(3), Z = 4. The Ag and Dy cations are coordinated by...

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Autor principal: Klein, Wilhelm
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439438/
https://www.ncbi.nlm.nih.gov/pubmed/37601568
http://dx.doi.org/10.1107/S2056989023004747
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author Klein, Wilhelm
author_facet Klein, Wilhelm
author_sort Klein, Wilhelm
collection PubMed
description Single crystals of Ag(3)Dy(2)(NO(3))(9) (tris­ilver didysprosium nona­nitrate) were obtained from a mixture of AgNO(3) and Dy(NO(3))(3)·5 H(2)O. The new compound crystallizes in space group P4(1)32 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å(3), Z = 4. The Ag and Dy cations are coordinated by five and six bidentate nitrate anions, respectively. Ag(3)Dy(2)(NO(3))(9) is isostructural to several compounds that include alkali metals or ammonium and lanthanide cations, but silver and dysprosium are included for the first time and feature the smallest ion radii observed for this structure type to date. Crystal structures of isotypic compounds are compared.
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spelling pubmed-104394382023-08-20 Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds Klein, Wilhelm Acta Crystallogr E Crystallogr Commun Research Communications Single crystals of Ag(3)Dy(2)(NO(3))(9) (tris­ilver didysprosium nona­nitrate) were obtained from a mixture of AgNO(3) and Dy(NO(3))(3)·5 H(2)O. The new compound crystallizes in space group P4(1)32 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å(3), Z = 4. The Ag and Dy cations are coordinated by five and six bidentate nitrate anions, respectively. Ag(3)Dy(2)(NO(3))(9) is isostructural to several compounds that include alkali metals or ammonium and lanthanide cations, but silver and dysprosium are included for the first time and feature the smallest ion radii observed for this structure type to date. Crystal structures of isotypic compounds are compared. International Union of Crystallography 2023-06-02 /pmc/articles/PMC10439438/ /pubmed/37601568 http://dx.doi.org/10.1107/S2056989023004747 Text en © Wilhelm Klein 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Klein, Wilhelm
Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title_full Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title_fullStr Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title_full_unstemmed Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title_short Crystal structure of Ag(3)Dy(2)(NO(3))(9) and qu­anti­tative comparison to isotypic compounds
title_sort crystal structure of ag(3)dy(2)(no(3))(9) and qu­anti­tative comparison to isotypic compounds
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439438/
https://www.ncbi.nlm.nih.gov/pubmed/37601568
http://dx.doi.org/10.1107/S2056989023004747
work_keys_str_mv AT kleinwilhelm crystalstructureofag3dy2no39andquantitativecomparisontoisotypiccompounds

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