Unified short syntheses of oxygenated tricyclic aromatic diterpenes by radical cyclization with a photoredox catalyst

The biomimetic two-phase strategy employing polyene cyclization and subsequent oxidation/substitution is an effective approach for divergent syntheses of [6-6-6]-tricyclic diterpenes. However, this strategy requires lengthy sequences for syntheses of oxygenated tricyclic aromatic abietane/podocarpan...

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Detalles Bibliográficos
Autores principales: Hashimoto, Riichi, Hanaya, Kengo, Sugai, Takeshi, Higashibayashi, Shuhei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442340/
https://www.ncbi.nlm.nih.gov/pubmed/37604953
http://dx.doi.org/10.1038/s42004-023-00979-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442340/
https://www.ncbi.nlm.nih.gov/pubmed/37604953
http://dx.doi.org/10.1038/s42004-023-00979-2

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