Allosteric control of olefin isomerization kinetics via remote metal binding and its mechanochemical analysis

Allosteric control of reaction thermodynamics is well understood, but the mechanisms by which changes in local geometries of receptor sites lower activation reaction barriers in electronically uncoupled, remote reaction moieties remain relatively unexplored. Here we report a molecular scaffold in wh...

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Detalles Bibliográficos
Autores principales: Yu, Yichen, O’Neill, Robert T., Boulatov, Roman, Widenhoefer, Ross A., Craig, Stephen L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442431/
https://www.ncbi.nlm.nih.gov/pubmed/37604905
http://dx.doi.org/10.1038/s41467-023-40842-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442431/
https://www.ncbi.nlm.nih.gov/pubmed/37604905
http://dx.doi.org/10.1038/s41467-023-40842-5

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