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Allosteric control of olefin isomerization kinetics via remote metal binding and its mechanochemical analysis
Allosteric control of reaction thermodynamics is well understood, but the mechanisms by which changes in local geometries of receptor sites lower activation reaction barriers in electronically uncoupled, remote reaction moieties remain relatively unexplored. Here we report a molecular scaffold in wh...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442431/ https://www.ncbi.nlm.nih.gov/pubmed/37604905 http://dx.doi.org/10.1038/s41467-023-40842-5 |