Experimental and Theoretical Exploration of the Kinetics and Thermodynamics of the Nucleophile-Induced Fragmentation of Ylidenenorbornadiene Carboxylates

[Image: see text] Ylidenenorbornadienes (YNDs), prepared by [4 + 2] cycloadditions between fulvenes and acetylene carboxylates, react with thiol nucleophiles to yield mixtures of four to eight diastereomers depending on the symmetry of the YND substrate. The mixtures of diastereomers fragment via a...

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Detalles Bibliográficos
Autores principales: Richardson, Abigail D., L’Heureux, Scott J., Henry, Ava M., McDonough, Elizabeth A., Fleischer, Cameron J., McMullen, Cameron C., Reynafarje, Trevor R., Guerrero, Gisele P., Williams, Quinn E., Zhou, Qingyang, Malouf, David M., Thurman, Spencer E., Soeller, Julia E., Sheng, Jerry Y., Medhurst, Erica A., Canales, Angel E., Cecil, Ty B., Houk, K. N., Costanzo, Philip J., Bercovici, Daniel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442913/
https://www.ncbi.nlm.nih.gov/pubmed/37535477
http://dx.doi.org/10.1021/acs.joc.3c00980

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