Mechanism of Cu-Catalyzed Iododeboronation: A Description of Ligand-Enabled Transmetalation, Disproportionation, and Turnover in Cu-Mediated Oxidative Coupling Reactions

[Image: see text] We report a combined experimental and computational study of the mechanism of the Cu-catalyzed arylboronic acid iododeboronation reaction. A combination of structural and density functional theory (DFT) analyses has allowed determination of the identity of the reaction precatalyst...

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Detalles Bibliográficos
Autores principales: Andrews, Matthew J., Carpentier, Ambre, Slawin, Alexandra M. Z., Cordes, David B., Macgregor, Stuart A., Watson, Allan J. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442916/
https://www.ncbi.nlm.nih.gov/pubmed/37614524
http://dx.doi.org/10.1021/acscatal.3c02839

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442916/
https://www.ncbi.nlm.nih.gov/pubmed/37614524
http://dx.doi.org/10.1021/acscatal.3c02839

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