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A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance

Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and...

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Detalles Bibliográficos
Autores principales: Khan, Jahangir, Ahmad, Rana Tariq Mehmood, Yu, Qiangmin, Liu, Heming, Khan, Usman, Liu, Bilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10443969/
https://www.ncbi.nlm.nih.gov/pubmed/37614964
http://dx.doi.org/10.1080/14686996.2023.2242262
Descripción
Sumario:Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and cycling performance. Considering this challenge, here we have designed a composite made of 2D MXene nanosheets and lanthanum oxide (La(2)O(3)) nanoparticles to overcome the limitations. The bifunctionality of La(2)O(3) nanoparticles prevents the restacking of MXene layers and enhances the electrochemical properties of the electrode due to its good Faradic characteristics. The specific capacitance of the La(2)O(3)/MXene composite electrode is 366 F/g at 1 A/g, which is 4.5 and 3 times higher than those of the individual La(2)O(3) and MXene. The composite electrode displays a capacitance retention of 96% after 1,000 cycles, which is due to synergistic effects between the two components and indicates the potential of La(2)O(3)/MXene composite for supercapacitors.