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A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance

Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and...

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Autores principales: Khan, Jahangir, Ahmad, Rana Tariq Mehmood, Yu, Qiangmin, Liu, Heming, Khan, Usman, Liu, Bilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10443969/
https://www.ncbi.nlm.nih.gov/pubmed/37614964
http://dx.doi.org/10.1080/14686996.2023.2242262
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author Khan, Jahangir
Ahmad, Rana Tariq Mehmood
Yu, Qiangmin
Liu, Heming
Khan, Usman
Liu, Bilu
author_facet Khan, Jahangir
Ahmad, Rana Tariq Mehmood
Yu, Qiangmin
Liu, Heming
Khan, Usman
Liu, Bilu
author_sort Khan, Jahangir
collection PubMed
description Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and cycling performance. Considering this challenge, here we have designed a composite made of 2D MXene nanosheets and lanthanum oxide (La(2)O(3)) nanoparticles to overcome the limitations. The bifunctionality of La(2)O(3) nanoparticles prevents the restacking of MXene layers and enhances the electrochemical properties of the electrode due to its good Faradic characteristics. The specific capacitance of the La(2)O(3)/MXene composite electrode is 366 F/g at 1 A/g, which is 4.5 and 3 times higher than those of the individual La(2)O(3) and MXene. The composite electrode displays a capacitance retention of 96% after 1,000 cycles, which is due to synergistic effects between the two components and indicates the potential of La(2)O(3)/MXene composite for supercapacitors.
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spelling pubmed-104439692023-08-23 A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance Khan, Jahangir Ahmad, Rana Tariq Mehmood Yu, Qiangmin Liu, Heming Khan, Usman Liu, Bilu Sci Technol Adv Mater Energy Materials Developing efficient electrode materials is a key towards high power electrochemical energy storage devices. Two-dimensional (2D) MXene shows excellent conductivity and electrochemical performance among other materials. However, the restacking of MXene layers may degrade their specific capacity and cycling performance. Considering this challenge, here we have designed a composite made of 2D MXene nanosheets and lanthanum oxide (La(2)O(3)) nanoparticles to overcome the limitations. The bifunctionality of La(2)O(3) nanoparticles prevents the restacking of MXene layers and enhances the electrochemical properties of the electrode due to its good Faradic characteristics. The specific capacitance of the La(2)O(3)/MXene composite electrode is 366 F/g at 1 A/g, which is 4.5 and 3 times higher than those of the individual La(2)O(3) and MXene. The composite electrode displays a capacitance retention of 96% after 1,000 cycles, which is due to synergistic effects between the two components and indicates the potential of La(2)O(3)/MXene composite for supercapacitors. Taylor & Francis 2023-08-18 /pmc/articles/PMC10443969/ /pubmed/37614964 http://dx.doi.org/10.1080/14686996.2023.2242262 Text en © 2023 The Author(s). Published by National Institute for Materials Science in partnership with Taylor & Francis Group. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The terms on which this article has been published allow the posting of the Accepted Manuscript in a repository by the author(s) or with their consent.
spellingShingle Energy Materials
Khan, Jahangir
Ahmad, Rana Tariq Mehmood
Yu, Qiangmin
Liu, Heming
Khan, Usman
Liu, Bilu
A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title_full A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title_fullStr A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title_full_unstemmed A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title_short A La(2)O(3)/MXene composite electrode for supercapacitors with improved capacitance and cycling performance
title_sort la(2)o(3)/mxene composite electrode for supercapacitors with improved capacitance and cycling performance
topic Energy Materials
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10443969/
https://www.ncbi.nlm.nih.gov/pubmed/37614964
http://dx.doi.org/10.1080/14686996.2023.2242262
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