Investigation of ortho-positronium annihilation for porous materials with different geometries and topologies

In this work, we present the results of the ortho-positronium (o-Ps) annihilation lifetimes and nitrogen adsorption measurements for different porous materials and an approach for describing the annihilation of o-Ps in a pore, which results in a surface-volume formula (SVF) for calculating the pore-related o-Ps lifetime. This proposed formula gives the relationship between the o-Ps annihilation rate and the effective pore radius, bulk composition, and pore structure, including pore geometry and topology. The pore-related o-Ps lifetimes of different materials calculated by the SVF are consistent with experimental results for both micro- and mesopores (and macropores) with different geometries and topologies. The SVF is convenient for calculations of pore dimensions for many cases of metal organic frameworks and zeolites. This approach enables us to fully explain the temperature dependence of the o-Ps annihilation lifetime over a wide temperature range, 20–700 K.