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Selective synthesis of germasila-adamantanes through germanium–silicon shift processes

The regioselective synthesis of germasila-adamantanes with the germanium atoms in the bridgehead positions is described starting from cyclic precursors by a cationic sila-Wagner–Meerwein (SWM) rearrangement reaction. The SWM rearrangement allows also a deliberate shift of germanium atoms from the pe...

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Detalles Bibliográficos
Autores principales:	Kühn, Steffen, Köstler, Benedikt, True, Celine, Albers, Lena, Wagner, Matthias, Müller, Thomas, Marschner, Christoph
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445437/ https://www.ncbi.nlm.nih.gov/pubmed/37621423 http://dx.doi.org/10.1039/d3sc03301e

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