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Role of mutations in a chemoenzymatic enantiodivergent C(sp(3))–H insertion: exploring the mechanism and origin of stereoselectivity
New-to-nature enzymes have emerged as powerful catalysts in recent years for streamlining various stereoselective organic transformations. While synthetic strategies employing engineered enzymes have witnessed proliferating success, there is limited clarity on the mechanistic front and more so when...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445471/ https://www.ncbi.nlm.nih.gov/pubmed/37621422 http://dx.doi.org/10.1039/d3sc02788k |