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Crystal engineering of high explosives through lone pair-π interactions: Insights for improving thermal safety

In this high-risk/high-reward study, we prepared complexes of a high explosive anion (picrate) with potentially explosive s-tetrazine-based ligands with the sole purpose of advancing the understanding of one of the weakest supramolecular forces: the lone pair-π interaction. This is a proof-of-concep...

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Detalles Bibliográficos
Autores principales: Savastano, Matteo, López de la Torre, María Dolores, Pagliai, Marco, Poggi, Giovanna, Ridi, Francesca, Bazzicalupi, Carla, Melguizo, Manuel, Bianchi, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10448033/
https://www.ncbi.nlm.nih.gov/pubmed/37636051
http://dx.doi.org/10.1016/j.isci.2023.107330