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Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil
As a potent antibacterial, antifungal or antiviral material, synthesis of quaternarized epoxidized soybean oil was demonstrated in this work. The first step of the synthesis is the reaction of epoxidized soybean oil (ESO) with 2-chloroethyl maleic acid (Cl-MA-ESO). The last step is quaternarization...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Scientific and Technological Research Council of Turkey (TUBITAK)
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10449244/ https://www.ncbi.nlm.nih.gov/pubmed/37638364 http://dx.doi.org/10.55730/1300-0527.3503 |
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author | GÜRBÜZ, Demet |
author_facet | GÜRBÜZ, Demet |
author_sort | GÜRBÜZ, Demet |
collection | PubMed |
description | As a potent antibacterial, antifungal or antiviral material, synthesis of quaternarized epoxidized soybean oil was demonstrated in this work. The first step of the synthesis is the reaction of epoxidized soybean oil (ESO) with 2-chloroethyl maleic acid (Cl-MA-ESO). The last step is quaternarization of this condensate with triethylamine (Q-MA-ESO). All the synthesized monomers were characterized by FTIR and (1)H NMR techniques. Homopolymer of the quaternarized derivative (Q-MA-ESO) was not obtained. However, styrene copolymers were obtained and characterized. Thermal properties of the copolymers were determined by TGA and DSC techniques. Additionally, swelling properties of the materials were also evaluated. The highest swelling ratio was observed in toluene. |
format | Online Article Text |
id | pubmed-10449244 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Scientific and Technological Research Council of Turkey (TUBITAK) |
record_format | MEDLINE/PubMed |
spelling | pubmed-104492442023-08-25 Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil GÜRBÜZ, Demet Turk J Chem Research Article As a potent antibacterial, antifungal or antiviral material, synthesis of quaternarized epoxidized soybean oil was demonstrated in this work. The first step of the synthesis is the reaction of epoxidized soybean oil (ESO) with 2-chloroethyl maleic acid (Cl-MA-ESO). The last step is quaternarization of this condensate with triethylamine (Q-MA-ESO). All the synthesized monomers were characterized by FTIR and (1)H NMR techniques. Homopolymer of the quaternarized derivative (Q-MA-ESO) was not obtained. However, styrene copolymers were obtained and characterized. Thermal properties of the copolymers were determined by TGA and DSC techniques. Additionally, swelling properties of the materials were also evaluated. The highest swelling ratio was observed in toluene. Scientific and Technological Research Council of Turkey (TUBITAK) 2022-10-04 /pmc/articles/PMC10449244/ /pubmed/37638364 http://dx.doi.org/10.55730/1300-0527.3503 Text en © TÜBİTAK https://creativecommons.org/licenses/by/4.0/This work is licensed under a Creative Commons Attribution 4.0 International License. |
spellingShingle | Research Article GÜRBÜZ, Demet Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title | Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title_full | Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title_fullStr | Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title_full_unstemmed | Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title_short | Quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
title_sort | quaternarization and polymerization of 2-chloroethyl maleate derivative of epoxidized soybean oil |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10449244/ https://www.ncbi.nlm.nih.gov/pubmed/37638364 http://dx.doi.org/10.55730/1300-0527.3503 |
work_keys_str_mv | AT gurbuzdemet quaternarizationandpolymerizationof2chloroethylmaleatederivativeofepoxidizedsoybeanoil |