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Metal–Ligand Proton Tautomerism, Electron Transfer, and C(sp(3))–H Activation by a 4-Pyridinyl-Pincer Iridium Hydride Complex

[Image: see text] The para-N-pyridyl-based PCP pincer proligand 3,5-bis(di-tert-butylphosphinomethyl)-2,6-dimethylpyridine (pN-(tBu)PCP-H) was synthesized and metalated to give the iridium complex (pN-(tBu)PCP)IrHCl (2-H). In marked contrast with its phenyl-based congeners, e.g., ((tBu)PCP)IrHCl and...

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Detalles Bibliográficos
Autores principales:	Bhatti, Tariq M., Kumar, Akshai, Parihar, Ashish, Moncy, Hellan K., Emge, Thomas J., Waldie, Kate M., Hasanayn, Faraj, Goldman, Alan S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10450815/ https://www.ncbi.nlm.nih.gov/pubmed/37552857 http://dx.doi.org/10.1021/jacs.3c03376

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