Cr(2)S(3)-Cr(2)O(3)/Poly-2-aminobenzene-1-thiol as a Highly Photocatalytic Material for Green Hydrogen Generation from Sewage Water

This study highlights the utilization of the Cr(2)S(3)-Cr(2)O(3)/P2ABT nanocomposite photoelectrode for efficient and highly sensitive photon absorption, enabling the generation of green hydrogen through the production of hot electrons upon illumination. The nanocomposite is synthesized via a one-pot reaction using K(2)Cr(2)O(7) and 2-aminobenzene-1-thiol monomer, and the presence of Cr(2)S(3)-Cr(2)O(3) is confirmed by XRD and XPS analysis within the composite. The optical properties of the Cr(2)S(3)-Cr(2)O(3)/poly-2-aminobenzene-1-thiol composite exhibit wide spectral coverage from UV to IR, with a bandgap of 1.6 eV. The diverse morphological behavior observed in the composite correlates with its optical properties, with the cleft spherical particles of the pure polymer transforming into rod-like structures embedded within the polymer matrix. The generated hydrogen gas demonstrates an impressive efficiency of 40.5 mole/10.cm(2).h through electrochemical testing. The current density (J(ph)) values are evaluated under different light frequencies using optical filters ranging from 730 to 340 nm, resulting in Jph values of 0.012 and 0.014 mA.cm(−2), respectively. These findings present a promising avenue as green hydrogen for industrial applications, leveraging the potential of the Cr(2)S(3)-Cr(2)O(3)/P2ABT nanocomposite photoelectrode.