Synthesis, Properties and Adsorption Kinetic Study of New Cross-Linked Composite Materials Based on Polyethylene Glycol Polyrotaxane and Polyisoprene/Semi-Rotaxane

New composite materials were prepared via cross-linking of polyethylene glycol/2-hydroxypropyl-β-cyclodextrins polyrotaxane (PEG/HPβCD) and polyisoprene/HPβCD semi-polyrotaxane (PI/HPβCD SR) with 1,6-hexamethylene diizocyanate (HMDI). Advanced instrumental methods (such WAXS (wide angle X-ray scattering), AFM (atomic force microscopy), SEM (scanning electron microscopy), and thermal and dynamic vapor sorption) were employed for the structural, morphological and thermal characterization of the resulting composite materials. The roughness parameters calculated using AFM indicate a smoother surface for the composite material with 10 wt% of PI/HPβCD SR, denoting that a homogeneous film was obtained. SEM analysis reveals porous morphologies for both composite materials and the pore sizes increase with the increasing concentration of PI/HPβCD SR in the matrix. Dynamic vapor sorption/desorption measurements and type IV isotherms confirmed the hydrophilic and porous materials, which are in agreement with SEM analysis. The composite with a higher PI/HPβCD SR concentration in the matrix showed increased thermal stability than that of the pure cross-linked material. This material was further tested as a sorbent for methylene blue (MB) dye removal from an aqueous solution. The adsorption capacity of the composite film was found to be 2.58 mg g(−1) at 25 °C.