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Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes
Ultrafiltration (UF) polymeric membranes are widely used in water treatment and support desalination and gas separation membranes. In this article, we enhance the performance of Polysulfone (PSF) mixed matrix membranes (MMMs) by dispersing different concentrations of thermally reduced graphene (TRG)...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10456715/ https://www.ncbi.nlm.nih.gov/pubmed/37623808 http://dx.doi.org/10.3390/membranes13080747 |
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author | Abdala, Omnya Nabeeh, Ahmed Rehman, Abdul Abdel-Wahab, Ahmed Hassan, Mohammad K. Abdala, Ahmed |
author_facet | Abdala, Omnya Nabeeh, Ahmed Rehman, Abdul Abdel-Wahab, Ahmed Hassan, Mohammad K. Abdala, Ahmed |
author_sort | Abdala, Omnya |
collection | PubMed |
description | Ultrafiltration (UF) polymeric membranes are widely used in water treatment and support desalination and gas separation membranes. In this article, we enhance the performance of Polysulfone (PSF) mixed matrix membranes (MMMs) by dispersing different concentrations of thermally reduced graphene (TRG) nanofillers. The UF PSF-TRG MMMs were fabricated via the phase inversion process, and the impact of TRG loading on the characteristics of the membrane, including hydrophilicity, porosity, roughness, and morphology, were analyzed using a contact angle measurement, atomic force microscopy (AFM), scanning electron microscopy (SEM), and dynamic mechanical analysis. Incorporating TRG into the PSF matrix led to favorable effects in the instantaneous de-mixing during phase inversion, increasing the porosity and hydrophilicity of MMMs and improving the mechanical properties of the membranes. Moreover, membrane performance was examined to remove dispersed oil from oil–water emulsion and support air-dehumidification membranes. MMM performance in terms of flux and oil rejection was superior to the control PSF membrane. Incorporating 0.25% TRG into PSF resulted in a 70% water flux increase and higher oil rejection compared to the control PSF membrane. As a support for air-dehumidification membranes, the MMM also demonstrated enhanced humidity reduction and an over 20% increase in water vapor permeance over the control PSF membrane. These results indicate that the PSF-TRG MMMs are an excellent candidate for reliable oil–water separation and as a support for air-dehumidification membranes. |
format | Online Article Text |
id | pubmed-10456715 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-104567152023-08-26 Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes Abdala, Omnya Nabeeh, Ahmed Rehman, Abdul Abdel-Wahab, Ahmed Hassan, Mohammad K. Abdala, Ahmed Membranes (Basel) Article Ultrafiltration (UF) polymeric membranes are widely used in water treatment and support desalination and gas separation membranes. In this article, we enhance the performance of Polysulfone (PSF) mixed matrix membranes (MMMs) by dispersing different concentrations of thermally reduced graphene (TRG) nanofillers. The UF PSF-TRG MMMs were fabricated via the phase inversion process, and the impact of TRG loading on the characteristics of the membrane, including hydrophilicity, porosity, roughness, and morphology, were analyzed using a contact angle measurement, atomic force microscopy (AFM), scanning electron microscopy (SEM), and dynamic mechanical analysis. Incorporating TRG into the PSF matrix led to favorable effects in the instantaneous de-mixing during phase inversion, increasing the porosity and hydrophilicity of MMMs and improving the mechanical properties of the membranes. Moreover, membrane performance was examined to remove dispersed oil from oil–water emulsion and support air-dehumidification membranes. MMM performance in terms of flux and oil rejection was superior to the control PSF membrane. Incorporating 0.25% TRG into PSF resulted in a 70% water flux increase and higher oil rejection compared to the control PSF membrane. As a support for air-dehumidification membranes, the MMM also demonstrated enhanced humidity reduction and an over 20% increase in water vapor permeance over the control PSF membrane. These results indicate that the PSF-TRG MMMs are an excellent candidate for reliable oil–water separation and as a support for air-dehumidification membranes. MDPI 2023-08-21 /pmc/articles/PMC10456715/ /pubmed/37623808 http://dx.doi.org/10.3390/membranes13080747 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Abdala, Omnya Nabeeh, Ahmed Rehman, Abdul Abdel-Wahab, Ahmed Hassan, Mohammad K. Abdala, Ahmed Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title | Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title_full | Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title_fullStr | Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title_full_unstemmed | Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title_short | Effect of Thermally Reduced Graphene on the Characteristics and Performance of Polysulfone Mixed Matrix Ultrafiltration Membranes |
title_sort | effect of thermally reduced graphene on the characteristics and performance of polysulfone mixed matrix ultrafiltration membranes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10456715/ https://www.ncbi.nlm.nih.gov/pubmed/37623808 http://dx.doi.org/10.3390/membranes13080747 |
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