Multicomponent X-ray Shielding Using Sulfated Cerium Oxide and Bismuth Halide Composites

Lead is the most widely used X-ray-shielding material, but it is heavy (density ≈ 11.34 g/cm(3)) and toxic. Therefore, the replacement of Pb with lightweight, ecofriendly materials would be beneficial, and such materials would have applications in medicine, electronics, and aerospace engineering. However, the shielding ability of Pb-free materials is significantly lower than that of Pb itself. To maximize the radiation attenuation of non-Pb-based shielding materials, a high-attenuation cross-section, normal to the incoming X-ray direction, must be achieved. In this study, we developed efficient X-ray-shielding materials composed of sulfated cerium oxide (S-CeO(2)) and bismuth halides. Crucially, the materials are lightweight and mechanically flexible because of the absence of heavy metals (for example, Pb and W). Further, by pre-forming the doped metal oxide as a porous sponge matrix, and then incorporating the bismuth halides into the porous matrix, uniform, compact, and intimate composites with a high-attenuation cross-section were achieved. Owing to the synergetic effect of the doped metal oxide and bismuth halides, the resultant thin (approximately 3 mm) and lightweight (0.85 g·cm(−3)) composite achieved an excellent X-ray-shielding rate of approximately 92% at 60 kV, one of the highest values reported for non-heavy-metal shielding materials.