Cargando…
Selective Functionalization of Carbonyl Closo-Decaborate [2-B(10)H(9)CO](−) with Building Block Properties via Grignard Reagents
A green, fast and selective approach for the synthesis of mono-substituted closo-decaborate derivatives [2-B(10)H(9)COR](2−) has been established via a nucleophilic addition reaction between the carbonyl derivative of closo-decaborate [2-B(10)H(9)CO](−) and the corresponding Grignard reagent RMgX, w...
Autores principales: | Mahfouz, Nadine, Abi-Ghaida, Fatima, Kotob, Wael, Mehdi, Ahmad, Naoufal, Daoud |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10458521/ https://www.ncbi.nlm.nih.gov/pubmed/37630327 http://dx.doi.org/10.3390/molecules28166076 |
Ejemplares similares
-
Grafting of Anionic Decahydro-Closo-Decaborate Clusters on Keggin and Dawson-Type Polyoxometalates: Syntheses, Studies in Solution, DFT Calculations and Electrochemical Properties
por: Diab, Manal, et al.
Publicado: (2022) -
Non-Covalent Interactions in the Crystal Structures of Perbrominated Sulfonium Derivatives of the closo-Decaborate Anion
por: Golubev, Aleksei V., et al.
Publicado: (2022) -
Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class
por: Voinova, Vera V., et al.
Publicado: (2021) -
Copper-Free Alternatives to Access Ketone Building
Blocks from Grignard Reagents
por: Taeschler, Christoph, et al.
Publicado: (2022) -
2-[(1-{[3-(dimethylazaniumyl)propyl]methylamino}ethylidene)azaniumyl]nonahydro-closo-decaborate dimethyl sulfoxide disolvate
por: Getman, Thomas D., et al.
Publicado: (2011)