Formation of Glycosyl Trichloroacetamides from Trichloroacetimidate Donors Occurs through an Intermolecular Aglycon Transfer Reaction

[Image: see text] To probe the reaction mechanism, underlying the rearrangement of oft-used trichloroacetimidate glycosyl donors into the corresponding anomeric trichloroacetamides, we have used a combination of (13)C- and (15)N-labeled glycosyl trichloroacetimidate donors in a series of crossover e...

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Detalles Bibliográficos
Autores principales: van de Vrande, Koen N. A., Filippov, Dmitri V., Codée, Jeroen D. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463224/
https://www.ncbi.nlm.nih.gov/pubmed/37578204
http://dx.doi.org/10.1021/acs.orglett.3c02196

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463224/
https://www.ncbi.nlm.nih.gov/pubmed/37578204
http://dx.doi.org/10.1021/acs.orglett.3c02196

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