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Formation of Glycosyl Trichloroacetamides from Trichloroacetimidate Donors Occurs through an Intermolecular Aglycon Transfer Reaction
[Image: see text] To probe the reaction mechanism, underlying the rearrangement of oft-used trichloroacetimidate glycosyl donors into the corresponding anomeric trichloroacetamides, we have used a combination of (13)C- and (15)N-labeled glycosyl trichloroacetimidate donors in a series of crossover e...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463224/ https://www.ncbi.nlm.nih.gov/pubmed/37578204 http://dx.doi.org/10.1021/acs.orglett.3c02196 |