Investigation of kinetics, isotherms, thermodynamics and photocatalytic regeneration of exfoliated graphitic carbon nitride/zeolite as dye adsorbent

A novel exfoliated graphitic carbon nitride and clinoptilolite nanocomposites (Ex.g-C(3)N(4)/CP and g-C(3)N(4)/CP with a various ratios of g-C(3)N(4) to CP) were prepared by facile method. This study evaluates the adsorption of methylene blue (MB) on the surface of synthesized adsorbents. The as-prepared composites were characterized by XRD, FT-IR, FESEM, BET and DRS. Batch experiments were carried out under various conditions, such as the amount of adsorbent and solution pH. The optimum batch experimental conditions were found under the response surface methodology. The Ex.g-C(3)N(4)/CP presented maximum removal of MB as compared to others. The removal efficiency of the as-prepared nanocomposite was significantly elevated owing to the synergistic effects. The adsorption capacities of MB (10 ppm) on Ex.g-C(3)N(4)/CP was 54.3 mg/g. The adsorption process by both composites (g-C(3)N(4)/CP and Ex.g-C(3)N(4)/CP) showed well-fitting with the Elovich kinetic model, and Langmuir isotherm. The thermodynamic study suggested that the adsorption of MB was a spontaneous and endothermic process. The reusability of g-C(3)N(4)/CP1:2 and Ex. g-C(3)N(4)/CP in removing of MB (10 ppm, pH = 9) was studied by photocatalytic regeneration under visible irradiation for three consecutive cycles. The results obtained from the experimental analyses showed that the removal of MB was easy treatment, eco-friendly, and high yield.