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Highly enantioselective synthesis of both tetrahydroquinoxalines and dihydroquinoxalinones via Rh–thiourea catalyzed asymmetric hydrogenation

Chiral tetrahydroquinoxalines and dihydroquinoxalinones represent the core structure of many bioactive molecules. Herein, a simple and efficient Rh–thiourea-catalyzed asymmetric hydrogenation for enantiopure tetrahydroquinoxalines and dihydroquinoxalinones was developed under 1 MPa H(2) pressure at...

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Detalles Bibliográficos
Autores principales:	Xu, Ana, Li, Chaoyi, Huang, Junrong, Pang, Heng, Zhao, Chengyao, Song, Lijuan, You, Hengzhi, Zhang, Xumu, Chen, Fen-Er
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466277/ https://www.ncbi.nlm.nih.gov/pubmed/37655018 http://dx.doi.org/10.1039/d3sc00803g

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