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A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C–N, C–O and C–S bonds

A guanidinato-stabilized binuclear yttrium carbyne complex [(PhCH(2))(2)NC(NC(6)H(3)(i)Pr(2)-2,6)(2)](2)Y(2)(μ(2)-Me)(AlMe(3))(2)(μ(4)-CH) (1) was synthesized via C–H bond activation and its versatile reactivities were investigated. Complex 1 underwent σ-bond metathesis with PhSSPh and nucleophilic...

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Detalles Bibliográficos
Autores principales:	Jiang, Wen, Kong, Feng, del Rosal, Iker, Li, Meng, Wang, Kai, Maron, Laurent, Zhang, Lixin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466373/ https://www.ncbi.nlm.nih.gov/pubmed/37655032 http://dx.doi.org/10.1039/d3sc03483f

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