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The Complex Reactivity of [(salen)Fe](2)(μ-O) with HBpin and Its Implications in Catalysis

[Image: see text] We report a detailed study into the method of precatalyst activation during alkyne cyclotrimerization. During these studies we have prepared a homologous series of Fe(III)-μ-oxo(salen) complexes and use a range of techniques including UV–vis, reaction monitoring studies, single cry...

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Detalles Bibliográficos
Autores principales: Hood, Thomas M., Lau, Samantha, Diefenbach, Martin, Firmstone, Leah, Mahon, Mary, Krewald, Vera, Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476159/
https://www.ncbi.nlm.nih.gov/pubmed/37671182
http://dx.doi.org/10.1021/acscatal.3c02898