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Regioselective synthesis of 3-nitroindoles under non-acidic and non-metallic conditions
An electrophilic substitution reaction, without acid and metal, of indole with ammonium tetramethylnitrate for accessing 3-nitroindole has been developed. In this protocol, trifluoroacetyl nitrate (CF(3)COONO(2)) was produced by metathesis of ammonium tetramethyl nitrate and trifluoroacetic anhydrid...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10478488/ https://www.ncbi.nlm.nih.gov/pubmed/37674482 http://dx.doi.org/10.1039/d3ra03193d |