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Photoinduced Reductive C–C and C–Heteroatom Couplings from Bis-cyclometalated Pt(IV) Alkynyl Complexes
[Image: see text] Unsymmetrical dicarboxylato complexes [Pt(tpy)(2)(O(2)CR)(2)] [tpy = cyclometalated 2-(p-tolyl)pyridine, R = Me, CF(3)] react with the terminal alkynes 4-methoxyphenylacetylene, phenylacetylene, 4-(trifluoromethyl)phenylacetylene or 3,5-difluorophenylacetylene in the presence of a...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10481375/ https://www.ncbi.nlm.nih.gov/pubmed/37616569 http://dx.doi.org/10.1021/acs.inorgchem.3c02162 |