M-type Gd(2)[Si(2)O(7)]

The title compound, digadolinium(III) oxidodisilicate, Gd(2)[Si(2)O(7)], was obtained in its M-type crystal structure after attempts to synthesize Gd(5)Br(3)[AsO(3)](4) as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu(2)[Si(2)O(7)]. This structure consists of l...

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Detalles Bibliográficos
Autores principales: Locke, Ralf Jules Christian, Schleid, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483536/
https://www.ncbi.nlm.nih.gov/pubmed/37693777
http://dx.doi.org/10.1107/S2414314623006545
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author Locke, Ralf Jules Christian
Schleid, Thomas
author_facet Locke, Ralf Jules Christian
Schleid, Thomas
author_sort Locke, Ralf Jules Christian
collection PubMed
description The title compound, digadolinium(III) oxidodisilicate, Gd(2)[Si(2)O(7)], was obtained in its M-type crystal structure after attempts to synthesize Gd(5)Br(3)[AsO(3)](4) as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu(2)[Si(2)O(7)]. This structure consists of layers of ecliptically arranged oxidodisilicate [Si(2)O(7)](6−) units separated from each other by bilayers consisting of Gd(III) cations. [Image: see text]
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spelling pubmed-104835362023-09-08 M-type Gd(2)[Si(2)O(7)] Locke, Ralf Jules Christian Schleid, Thomas IUCrdata Data Reports The title compound, digadolinium(III) oxidodisilicate, Gd(2)[Si(2)O(7)], was obtained in its M-type crystal structure after attempts to synthesize Gd(5)Br(3)[AsO(3)](4) as a by-product from fused silica ampoules. It crystallizes isotypically with M-type Eu(2)[Si(2)O(7)]. This structure consists of layers of ecliptically arranged oxidodisilicate [Si(2)O(7)](6−) units separated from each other by bilayers consisting of Gd(III) cations. [Image: see text] International Union of Crystallography 2023-08-01 /pmc/articles/PMC10483536/ /pubmed/37693777 http://dx.doi.org/10.1107/S2414314623006545 Text en © Locke and Schleid 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Locke, Ralf Jules Christian
Schleid, Thomas
M-type Gd(2)[Si(2)O(7)]
title M-type Gd(2)[Si(2)O(7)]
title_full M-type Gd(2)[Si(2)O(7)]
title_fullStr M-type Gd(2)[Si(2)O(7)]
title_full_unstemmed M-type Gd(2)[Si(2)O(7)]
title_short M-type Gd(2)[Si(2)O(7)]
title_sort m-type gd(2)[si(2)o(7)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483536/
https://www.ncbi.nlm.nih.gov/pubmed/37693777
http://dx.doi.org/10.1107/S2414314623006545
work_keys_str_mv AT lockeralfjuleschristian mtypegd2si2o7
AT schleidthomas mtypegd2si2o7

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