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Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer

In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and u...

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Detalles Bibliográficos
Autores principales: Jia, Jason, LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483537/
https://www.ncbi.nlm.nih.gov/pubmed/37693780
http://dx.doi.org/10.1107/S2414314623006594
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author Jia, Jason
LaDuca, Robert L.
author_facet Jia, Jason
LaDuca, Robert L.
author_sort Jia, Jason
collection PubMed
description In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butyl­isophthalate ligands. One of the Zn atoms displays a tetra­hedral coordination environment, while the other Zn atom adopts a five-coordinate geometry inter­mediate between square pyramidal and trigonal bipyramidal. Additionally, O—H⋯O hydrogen-bonding patterns involving the water mol­ecules of crystallization serve as a structure-stabilizing element by aggregating the double-strand motifs. [Image: see text]
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spelling pubmed-104835372023-09-08 Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer Jia, Jason LaDuca, Robert L. IUCrdata Data Reports In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butyl­isophthalate ligands. One of the Zn atoms displays a tetra­hedral coordination environment, while the other Zn atom adopts a five-coordinate geometry inter­mediate between square pyramidal and trigonal bipyramidal. Additionally, O—H⋯O hydrogen-bonding patterns involving the water mol­ecules of crystallization serve as a structure-stabilizing element by aggregating the double-strand motifs. [Image: see text] International Union of Crystallography 2023-08-04 /pmc/articles/PMC10483537/ /pubmed/37693780 http://dx.doi.org/10.1107/S2414314623006594 Text en © Jia and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Jia, Jason
LaDuca, Robert L.
Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title_full Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title_fullStr Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title_full_unstemmed Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title_short Poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
title_sort poly[[aqua­[μ(2)-1,3-bis­(pyridin-4-yl)urea-κ(2) n (4):n (4′)]bis­(μ(3)-5-tert-butyl­isophthalato-κ(3) o (1):o (1′):o (3))dizinc(ii)] trihydrate], a double-strand coordination polymer
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483537/
https://www.ncbi.nlm.nih.gov/pubmed/37693780
http://dx.doi.org/10.1107/S2414314623006594
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