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Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer
In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and u...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483537/ https://www.ncbi.nlm.nih.gov/pubmed/37693780 http://dx.doi.org/10.1107/S2414314623006594 |
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author | Jia, Jason LaDuca, Robert L. |
author_facet | Jia, Jason LaDuca, Robert L. |
author_sort | Jia, Jason |
collection | PubMed |
description | In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butylisophthalate ligands. One of the Zn atoms displays a tetrahedral coordination environment, while the other Zn atom adopts a five-coordinate geometry intermediate between square pyramidal and trigonal bipyramidal. Additionally, O—H⋯O hydrogen-bonding patterns involving the water molecules of crystallization serve as a structure-stabilizing element by aggregating the double-strand motifs. [Image: see text] |
format | Online Article Text |
id | pubmed-10483537 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-104835372023-09-08 Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer Jia, Jason LaDuca, Robert L. IUCrdata Data Reports In the title compound, {[Zn(2)(C(12)H(12)O(4))(2)(C(11)H(10)N(4)O)(H(2)O)]·3H(2)O}( n ), monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N—H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butylisophthalate ligands. One of the Zn atoms displays a tetrahedral coordination environment, while the other Zn atom adopts a five-coordinate geometry intermediate between square pyramidal and trigonal bipyramidal. Additionally, O—H⋯O hydrogen-bonding patterns involving the water molecules of crystallization serve as a structure-stabilizing element by aggregating the double-strand motifs. [Image: see text] International Union of Crystallography 2023-08-04 /pmc/articles/PMC10483537/ /pubmed/37693780 http://dx.doi.org/10.1107/S2414314623006594 Text en © Jia and LaDuca 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Jia, Jason LaDuca, Robert L. Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2) N (4):N (4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3) O (1):O (1′):O (3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title | Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
N
(4):N
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
O
(1):O
(1′):O
(3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title_full | Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
N
(4):N
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
O
(1):O
(1′):O
(3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title_fullStr | Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
N
(4):N
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
O
(1):O
(1′):O
(3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title_full_unstemmed | Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
N
(4):N
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
O
(1):O
(1′):O
(3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title_short | Poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
N
(4):N
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
O
(1):O
(1′):O
(3))dizinc(II)] trihydrate], a double-strand coordination polymer |
title_sort | poly[[aqua[μ(2)-1,3-bis(pyridin-4-yl)urea-κ(2)
n
(4):n
(4′)]bis(μ(3)-5-tert-butylisophthalato-κ(3)
o
(1):o
(1′):o
(3))dizinc(ii)] trihydrate], a double-strand coordination polymer |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483537/ https://www.ncbi.nlm.nih.gov/pubmed/37693780 http://dx.doi.org/10.1107/S2414314623006594 |
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