μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate

The reaction of CuCl(2) with 1,6-diphenyl-1,3,5,6-hexa­netetrone and 2,2′-bi­pyridine (bipy) in ethanol gave crystals of the corresponding bimetallic complex, [Cu(2)(C(18)H(12)O(4))Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O. The mol­ecule is centrosymmetric with each Cu(II) ion coordinated to two oxygen atoms...

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Detalles Bibliográficos
Autores principales: Nye, Luke, Telfer, Shane G., Turnbull, Mark M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483540/
https://www.ncbi.nlm.nih.gov/pubmed/37693791
http://dx.doi.org/10.1107/S2414314623007137
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author Nye, Luke
Telfer, Shane G.
Turnbull, Mark M.
author_facet Nye, Luke
Telfer, Shane G.
Turnbull, Mark M.
author_sort Nye, Luke
collection PubMed
description The reaction of CuCl(2) with 1,6-diphenyl-1,3,5,6-hexa­netetrone and 2,2′-bi­pyridine (bipy) in ethanol gave crystals of the corresponding bimetallic complex, [Cu(2)(C(18)H(12)O(4))Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O. The mol­ecule is centrosymmetric with each Cu(II) ion coordinated to two oxygen atoms from the tetronediate, two nitro­gen atoms from a bipy ligand and one coordinated chloride ion. A water mol­ecule of crystallization forms hydrogen bonds to the chloride ions, linking the mol­ecules into a chain parallel to the bc-face diagonal. [Image: see text]
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spelling pubmed-104835402023-09-08 μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate Nye, Luke Telfer, Shane G. Turnbull, Mark M. IUCrdata Data Reports The reaction of CuCl(2) with 1,6-diphenyl-1,3,5,6-hexa­netetrone and 2,2′-bi­pyridine (bipy) in ethanol gave crystals of the corresponding bimetallic complex, [Cu(2)(C(18)H(12)O(4))Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O. The mol­ecule is centrosymmetric with each Cu(II) ion coordinated to two oxygen atoms from the tetronediate, two nitro­gen atoms from a bipy ligand and one coordinated chloride ion. A water mol­ecule of crystallization forms hydrogen bonds to the chloride ions, linking the mol­ecules into a chain parallel to the bc-face diagonal. [Image: see text] International Union of Crystallography 2023-08-30 /pmc/articles/PMC10483540/ /pubmed/37693791 http://dx.doi.org/10.1107/S2414314623007137 Text en © Nye et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Nye, Luke
Telfer, Shane G.
Turnbull, Mark M.
μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title_full μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title_fullStr μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title_full_unstemmed μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title_short μ-1,6-Dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(II)] dihydrate
title_sort μ-1,6-dioxo-1,6-di­phenyl­hexane-3,4-diolato-bis­[(2,2′-bi­pyridine)­chlorido­copper(ii)] dihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483540/
https://www.ncbi.nlm.nih.gov/pubmed/37693791
http://dx.doi.org/10.1107/S2414314623007137
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AT turnbullmarkm m16dioxo16diphenylhexane34diolatobis22bipyridinechloridocopperiidihydrate

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