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2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol

In the title compound, C(22)H(22)N(2)O(4), the central pyrazoline ring exhibits a nearly planar structure (r.m.s. deviation = 0.025 Å) despite having two sp (3) carbon atoms. The pyrazoline ring subtends dihedral angles of 4.61 (1) and 87.31 (1)° with the pendant benzene ring and naphthalene ring sy...

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Autor principal: Sung, Jiha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483541/
https://www.ncbi.nlm.nih.gov/pubmed/37693784
http://dx.doi.org/10.1107/S2414314623006685
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author Sung, Jiha
author_facet Sung, Jiha
author_sort Sung, Jiha
collection PubMed
description In the title compound, C(22)H(22)N(2)O(4), the central pyrazoline ring exhibits a nearly planar structure (r.m.s. deviation = 0.025 Å) despite having two sp (3) carbon atoms. The pyrazoline ring subtends dihedral angles of 4.61 (1) and 87.31 (1)° with the pendant benzene ring and naphthalene ring system, respectively. The dihedral angle between the planes of the benzene ring and the naphthalene ring system is 89.76 (2)°. An intra­molecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, inversion dimers formed by pairwise weak N—H⋯N hydrogen bonds generate R (2) (2)(4) loops and the dimers are linked by pairwise C—H⋯O hydrogen bonds [which generate R (2) (2)(8) loops] into [100] chains. [Image: see text]
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spelling pubmed-104835412023-09-08 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol Sung, Jiha IUCrdata Data Reports In the title compound, C(22)H(22)N(2)O(4), the central pyrazoline ring exhibits a nearly planar structure (r.m.s. deviation = 0.025 Å) despite having two sp (3) carbon atoms. The pyrazoline ring subtends dihedral angles of 4.61 (1) and 87.31 (1)° with the pendant benzene ring and naphthalene ring system, respectively. The dihedral angle between the planes of the benzene ring and the naphthalene ring system is 89.76 (2)°. An intra­molecular O—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, inversion dimers formed by pairwise weak N—H⋯N hydrogen bonds generate R (2) (2)(4) loops and the dimers are linked by pairwise C—H⋯O hydrogen bonds [which generate R (2) (2)(8) loops] into [100] chains. [Image: see text] International Union of Crystallography 2023-08-10 /pmc/articles/PMC10483541/ /pubmed/37693784 http://dx.doi.org/10.1107/S2414314623006685 Text en © Jiha Sung 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sung, Jiha
2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title_full 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title_fullStr 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title_full_unstemmed 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title_short 2-[5-(2,3-Di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]-3-meth­oxy­phenol
title_sort 2-[5-(2,3-di­meth­oxy­naphthalen-1-yl)-4,5-di­hydro-1h-pyrazol-3-yl]-3-meth­oxy­phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483541/
https://www.ncbi.nlm.nih.gov/pubmed/37693784
http://dx.doi.org/10.1107/S2414314623006685
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