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Poly[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine]bis[μ(3)-4-(2-carboxylatoethyl)benzoato]dicopper(II)]
In the title coordination polymer, [Cu(2)(C(9)H(6)O(4))(2)(C(16)H(20)N(4))]( n ), the Cu(II) atoms in {NO(4)} square-pyramidal coordination environments are conjoined into diperiodic coordination polymer slabs by the full span of the bridging 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) and 4-(car...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483545/ https://www.ncbi.nlm.nih.gov/pubmed/37693782 http://dx.doi.org/10.1107/S2414314623007459 |
Sumario: | In the title coordination polymer, [Cu(2)(C(9)H(6)O(4))(2)(C(16)H(20)N(4))]( n ), the Cu(II) atoms in {NO(4)} square-pyramidal coordination environments are conjoined into diperiodic coordination polymer slabs by the full span of the bridging 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) and 4-(carboxylethyl)benzoate (ceb) ligands. The slab motifs are expanded into the full crystal structure by means of longer-range C—H⋯O attractive interactions. [Image: see text] |
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