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Synthesis, crystal structure and Hirshfeld surface analysis of a copper(II) complex involving 3-methyl­benzoate and 2,2′-bi­pyridine ligands

3-Methyl­benzoic acid (3-mbH) and 2,2′-bi­pyridine (bipy) reacted with a cop­per(II) salt forming a new mixed ligand complex, aqua­(2,2′-bi­pyridine-κ(2) N,N′)bis­(3-methyl­benzoato)-κ(2) O,O′;κO-copper(II) 0.68-hydrate, [Cu(C(8)H(7)O(2))(2)(C(10)H(8)N(2))(H(2)O)]·0.68H(2)O or [Cu(3-mb)(2)(bipy)(H(2...

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Detalles Bibliográficos
Autor principal: Qadir, Adnan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10483552/
https://www.ncbi.nlm.nih.gov/pubmed/37693670
http://dx.doi.org/10.1107/S2056989023006904
Descripción
Sumario:3-Methyl­benzoic acid (3-mbH) and 2,2′-bi­pyridine (bipy) reacted with a cop­per(II) salt forming a new mixed ligand complex, aqua­(2,2′-bi­pyridine-κ(2) N,N′)bis­(3-methyl­benzoato)-κ(2) O,O′;κO-copper(II) 0.68-hydrate, [Cu(C(8)H(7)O(2))(2)(C(10)H(8)N(2))(H(2)O)]·0.68H(2)O or [Cu(3-mb)(2)(bipy)(H(2)O)]·0.68H(2)O. The coord­ination environment of Cu(II) is a distorted octa­hedron. The metal atom is attached to two 3-mb moieties, which bind in monodentate and bidentate fashions. One of the 3-mb units is disordered. The coordination environment is completed by one bipy ligand and a water mol­ecule. A second water mol­ecule is outside the coordination sphere of the Cu(II) atom and its occupancy refined to 0.68. The structure consists of chains along the b-axis direction formed by complex units joined via hydrogen bonds between the coordinated water mol­ecule and an O atom of a coordinated 3-mb unit. Hirshfeld surface analysis indicates that the most abundant contacts are H⋯H (56.8%), H⋯C/C⋯H (21.7%) and H⋯O/O⋯H (13.7%).