In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive chang...

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Detalles Bibliográficos
Autores principales: Goodall, Joe C., Sajjad, M. Arif, Thompson, Emily A., Page, Samuel J., Kerrigan, Adam M., Jenkins, Huw T., Lynam, Jason M., Macgregor, Stuart A., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10484290/
https://www.ncbi.nlm.nih.gov/pubmed/37602809
http://dx.doi.org/10.1039/d3cc03201a
Descripción
Sumario:The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr(F)(4)] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

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