In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive chang...

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Autores principales: Goodall, Joe C., Sajjad, M. Arif, Thompson, Emily A., Page, Samuel J., Kerrigan, Adam M., Jenkins, Huw T., Lynam, Jason M., Macgregor, Stuart A., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10484290/
https://www.ncbi.nlm.nih.gov/pubmed/37602809
http://dx.doi.org/10.1039/d3cc03201a
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author Goodall, Joe C.
Sajjad, M. Arif
Thompson, Emily A.
Page, Samuel J.
Kerrigan, Adam M.
Jenkins, Huw T.
Lynam, Jason M.
Macgregor, Stuart A.
Weller, Andrew S.
author_facet Goodall, Joe C.
Sajjad, M. Arif
Thompson, Emily A.
Page, Samuel J.
Kerrigan, Adam M.
Jenkins, Huw T.
Lynam, Jason M.
Macgregor, Stuart A.
Weller, Andrew S.
author_sort Goodall, Joe C.
collection PubMed
description The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr(F)(4)] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.
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spelling pubmed-104842902023-09-08 In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes Goodall, Joe C. Sajjad, M. Arif Thompson, Emily A. Page, Samuel J. Kerrigan, Adam M. Jenkins, Huw T. Lynam, Jason M. Macgregor, Stuart A. Weller, Andrew S. Chem Commun (Camb) Chemistry The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr(F)(4)] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity. The Royal Society of Chemistry 2023-08-07 /pmc/articles/PMC10484290/ /pubmed/37602809 http://dx.doi.org/10.1039/d3cc03201a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Goodall, Joe C.
Sajjad, M. Arif
Thompson, Emily A.
Page, Samuel J.
Kerrigan, Adam M.
Jenkins, Huw T.
Lynam, Jason M.
Macgregor, Stuart A.
Weller, Andrew S.
In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title_full In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title_fullStr In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title_full_unstemmed In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title_short In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
title_sort in crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10484290/
https://www.ncbi.nlm.nih.gov/pubmed/37602809
http://dx.doi.org/10.1039/d3cc03201a
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