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In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
The group 7 complexes [M(κ(3)-2,6-(R(2)PO)(2)C(5)H(3)N)(CO)(2)L][BAr(F)(4)] [M = Mn, R = (i)Pr, L = THF; M = Re, R = (t)Bu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive chang...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10484290/ https://www.ncbi.nlm.nih.gov/pubmed/37602809 http://dx.doi.org/10.1039/d3cc03201a |