Cargando…

Access to Enantiomerically Pure P-Chiral 1-Phosphanorbornane Silyl Ethers

Sulfur-protected enantiopure P-chiral 1-phosphanorbornane silyl ethers 5a,b are obtained in high yields via the reaction of the hydroxy group of P-chiral 1-phosphanorbornane alcohol 4 with tert-butyldimethylsilyl chloride (TBDMSCl) and triphenylsilyl chloride (TPSCl). The corresponding optically pur...

Descripción completa

Detalles Bibliográficos
Autores principales:	Ramazanova, Kyzgaldak, Chakrabortty, Soumyadeep, Kallmeier, Fabian, Kretzschmar, Nadja, Tin, Sergey, Lönnecke, Peter, de Vries, Johannes G., Hey-Hawkins, Evamarie
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10488433/ https://www.ncbi.nlm.nih.gov/pubmed/37687039 http://dx.doi.org/10.3390/molecules28176210

Ejemplares similares

Synthesis of P-stereogenic 1-phosphanorbornane-derived phosphine–phosphite ligands and application in asymmetric catalysis
por: Ramazanova, Kyzgaldak, et al.
Publicado: (2023)

Ring-Opening Reaction of 1-Phospha-2-Azanorbornenes via P-N Bond Cleavage and Reversibility Studies
por: Ramazanova, Kyzgaldak, et al.
Publicado: (2023)

Asymmetric 1,3-dipolar cycloaddition reaction of chiral 1-alkyl-1,2-diphospholes with diphenyldiazomethane
por: Ganushevich, Yulia, et al.
Publicado: (2020)

Enantiomeric Separation and Determination of the Enantiomeric Impurity of Armodafinil by Capillary Electrophoresis with Sulfobutyl Ether-β-cyclodextrin as Chiral Selector
por: Wang, Wei, et al.
Publicado: (2011)

Silver(I) Complexes of Two Flexible Bis‐phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands
por: Boar, Paul, et al.
Publicado: (2020)

Unusual Racemization of Tertiary P‐Chiral Ferrocenyl Phosphines
por: Popp, John, et al.
Publicado: (2020)

[Disulfanediylbis(ferrocenylthiophosphinato)-κ(2) O,O]titanocene tetrahydrofuran trisolvate
por: Karakus, Mehmet, et al.
Publicado: (2012)

Cobalt‐Catalyzed Dehydrogenative C−H Silylation of Alkynylsilanes
por: Stachowiak, Hanna, et al.
Publicado: (2021)

Enlargement of a Modular System—Synthesis and Characterization of an s-Triazine-Based Carboxylic Acid Ester Bearing a Galactopyranosyl Moiety and an Enormous Boron Load
por: Kellert, Martin, et al.
Publicado: (2019)

Ruthenium-Catalyzed Dehydrogenative Intermolecular O-H/Si-H/C-H Silylation: Synthesis of (E)-Alkenyl Silyl-Ether and Silyl-Ether Heterocycle
por: Huang, Ziwei, et al.
Publicado: (2023)

Enantiomeric Recognition and Separation by Chiral Nanoparticles
por: Gogoi, Ankur, et al.
Publicado: (2019)

Catalytic Activity Towards Hydrogen Evolution Dependent of the Degree of Conjugation and Absorption of Six Organic Chromophores
por: Aleksovska, Angela, et al.
Publicado: (2020)

Facile Arene Ligand Exchange in p-Cymene Ruthenium(II) Complexes of Tertiary P-Chiral Ferrocenyl Phosphines
por: Popp, John, et al.
Publicado: (2019)

Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
por: Supranovich, Vyacheslav I, et al.
Publicado: (2020)

Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
por: Grosu, Ioana Georgeta, et al.
Publicado: (2015)

Ruthenacarborane–Phenanthroline Derivatives as Potential Metallodrugs
por: Kellert, Martin, et al.
Publicado: (2020)

Easy Access to Enantiomerically Pure Heterocyclic Silicon‐Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release
por: Fontana, Nicolò, et al.
Publicado: (2021)

Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition
por: Tiritan, Maria Elizabeth, et al.
Publicado: (2020)

Enantiomeric Separation of New Chiral Azole Compounds
por: Kenari, Marziyeh E., et al.
Publicado: (2021)

Triphenyltin(IV) Carboxylates with Exceptionally High Cytotoxicity against Different Breast Cancer Cell Lines
por: Predarska, Ivana, et al.
Publicado: (2023)

FLP‐Catalyzed Transfer Hydrogenation of Silyl Enol Ethers
por: Khan, Imtiaz, et al.
Publicado: (2018)

Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers
por: Zhou, Hui, et al.
Publicado: (2022)

Catalytic asymmetric defluorinative allylation of silyl enol ethers
por: Duran, Jordi, et al.
Publicado: (2023)

Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization
por: Fichter, Sebastian, et al.
Publicado: (2020)

Towards Enantiomerically Pure Unnatural α-Amino Acids via Photoredox Catalytic 1,4-Additions to a Chiral Dehydroalanine
por: Oroz, Paula, et al.
Publicado: (2022)

Metallodrugs against Breast Cancer: Combining the Tamoxifen Vector with Platinum(II) and Palladium(II) Complexes
por: Kazimir, Aleksandr, et al.
Publicado: (2023)

Synergistic Catalysis in Heterobimetallic Complexes for Homogeneous Carbon Dioxide Hydrogenation
por: Fickenscher, Zeno B. G., et al.
Publicado: (2023)

Correction: Kazimir et al. Metallodrugs against Breast Cancer: Combining the Tamoxifen Vector with Platinum(II) and Palladium(II) Complexes. Pharmaceutics 2023, 15, 682
por: Kazimir, Aleksandr, et al.
Publicado: (2023)

Trifluoromethylthiolation, Trifluoromethylation, and Arylation Reactions of Difluoro Enol Silyl Ethers
por: Jiang, Xingguo, et al.
Publicado: (2020)

NMR analysis of the enantiomeric purity of chiral diols by a new chiral boron agent
por: Zhang, Xuebo, et al.
Publicado: (2022)

Silylated-Acetylated Cyclodextrins as Chiral Sensors for the Enantiodiscrimination of Fluorinated Anesthetics
por: Recchimurzo, Alessandra, et al.
Publicado: (2023)

Modular Synthetic Approach to Carboranyl‒Biomolecules Conjugates
por: Kellert, Martin, et al.
Publicado: (2021)

Preparation and facile addition reactions of iminium salts derived from amino ketene silyl acetal and amino silyl enol ether
por: Shimizu, Makoto, et al.
Publicado: (2020)

Fluorination of silyl prosthetic groups by fluorine mediated silyl ether linker cleavage: a concept study with conditions applicable in radiofluorination
por: Kramer, Carsten Sven, et al.
Publicado: (2022)

Synthesis of enantiomerically pure alcohols and amines via biocatalytic deracemisation methods
por: Musa, Musa M., et al.
Publicado: (2019)

Bio-Approach for Obtaining Enantiomerically Pure Clopidogrel with the Use of Ionic Liquids
por: Chałupka, Joanna, et al.
Publicado: (2023)

Enantiomeric Resolution and Docking Studies of Chiral Xanthonic Derivatives on Chirobiotic Columns
por: Phyo, Ye‛ Zaw, et al.
Publicado: (2018)

Enantiomerization of Axially Chiral Biphenyls: Polarizable MD Simulations in Water and Butylmethylether
por: Zeindlhofer, Veronika, et al.
Publicado: (2020)

Helical springs as a color indicator for determining chirality and enantiomeric excess
por: Maeda, Katsuhiro, et al.
Publicado: (2021)

Bipolar Electrochemical Measurement of Enantiomeric Excess with Inherently Chiral Polymer Actuators
por: Arnaboldi, Serena, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_f7j0cs1548vi3ir1nbi3u83tg1