Synthesis, Reactivity and Coordination Chemistry of Group 9 PBP Boryl Pincer Complexes: [(PBP)M(PMe(3))(n)] (M = Co, Rh, Ir; n = 1, 2)

The unsymmetrical diborane(4) derivative [(d(CH(2)P(iPr)(2))abB)–Bpin] (1) proved to be a versatile PBP boryl pincer ligand precursor for Co(I) (2a, 4a), Rh(I) (2–3b) and Ir(I/III) (2–3c, 5–6c) complexes, in particular of the types [(d(CH(2)P(iPr)(2))abB)M(PMe(3))(2)] (2a–c) and [(d(CH(2)P(iPr)(2))a...

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Detalles Bibliográficos
Autores principales: Rutz, Philipp M., Grunenberg, Jörg, Kleeberg, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10488511/
https://www.ncbi.nlm.nih.gov/pubmed/37687020
http://dx.doi.org/10.3390/molecules28176191

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10488511/
https://www.ncbi.nlm.nih.gov/pubmed/37687020
http://dx.doi.org/10.3390/molecules28176191

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