Homogeneous Nanostructured VO(2)@SiO(2) as an Anti-Reflecting Layer in the Visible/Near Infrared Wavelength

Low reflectivity is of great significance to photoelectric devices, optical displays, solar cells, photocatalysis and other fields. In this paper, vanadium oxide is deposited on pattern SiO(2) via atomic layer deposition and then annealed to characterize and analyze the anti-reflection effect. Scanning electron microscope (SEM) images indicate that the as-deposited VO(x) film has the advantages of uniformity and controllability. After annealing treatment, the VO(2)@pattern SiO(2) has fewer crevices compared with VO(2) on the accompanied planar SiO(2) substrate. Raman results show that there is tiny homogeneous stress in the VO(2) deposited on pattern SiO(2), which dilutes the shrinkage behavior of the crystallization process. The optical reflection spectra indicate that the as-deposited VO(x)@pattern SiO(2) has an anti-reflection effect due to the combined mechanism of the trapping effect and the effective medium theory. After annealing treatment, the weighted average reflectance diminished to 1.46% in the visible near-infrared wavelength range of 650–1355 nm, in which the absolute reflectance is less than 2%. Due to the multiple scattering effect caused by the tiny cracks generated through annealing, the anti-reflection effect of VO(2)@pattern SiO(2) is superior to that of VO(x)@pattern SiO(2). The ultra-low reflection frequency domain amounts to 705 nm, and the lowest absolute reflectance emerges at 1000 nm with an astonishing value of 0.86%. The prepared anti-reflective materials have significant application prospects in the field of intelligent optoelectronic devices due to the controllability of atomic layer deposition (ALD) and phase transition characteristics of VO(2).