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Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation

This work reports on the photocatalytic activity of tin oxide (SnO(2))-doped magnesium (Mg) and fluorine (F) nanoparticles for methyl orange and safranin dye degradation under sunlight irradiation. Nanocatalysis-induced dye degradation was examined using UV–visible spectroscopy and a pseudo-first-or...

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Detalles Bibliográficos
Autores principales: Velmurugan, G., Ganapathi Raman, R., Sivaprakash, P., Viji, A., Cho, Shin Hum, Kim, Ikhyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10489931/
https://www.ncbi.nlm.nih.gov/pubmed/37687002
http://dx.doi.org/10.3390/nano13172494
Descripción
Sumario:This work reports on the photocatalytic activity of tin oxide (SnO(2))-doped magnesium (Mg) and fluorine (F) nanoparticles for methyl orange and safranin dye degradation under sunlight irradiation. Nanocatalysis-induced dye degradation was examined using UV–visible spectroscopy and a pseudo-first-order kinetics model. The results indicate that the prepared nanoparticles exhibit superior photocatalytic activity, and the degradation of methyl orange (MO) dye is approximately 82%. In contrast, the degradation of safranin dye is 96% in the same time interval of 105 min. The calculated crystallite size of the SnO(2)–Mg–F nanocomposite is 29.5 nm, which respects the particle size found in the DLS analysis with a tetragonal structure and spherical morphology affirmed. The optical characteristics were assessed, and their respective bandgap energies were determined to be 3.6 eV. The influence of F in Mg and SnO(2) is recognized with the XRD and FT-IR spectra of the prepared particles.