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Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation

This work reports on the photocatalytic activity of tin oxide (SnO(2))-doped magnesium (Mg) and fluorine (F) nanoparticles for methyl orange and safranin dye degradation under sunlight irradiation. Nanocatalysis-induced dye degradation was examined using UV–visible spectroscopy and a pseudo-first-or...

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Autores principales: Velmurugan, G., Ganapathi Raman, R., Sivaprakash, P., Viji, A., Cho, Shin Hum, Kim, Ikhyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10489931/
https://www.ncbi.nlm.nih.gov/pubmed/37687002
http://dx.doi.org/10.3390/nano13172494
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author Velmurugan, G.
Ganapathi Raman, R.
Sivaprakash, P.
Viji, A.
Cho, Shin Hum
Kim, Ikhyun
author_facet Velmurugan, G.
Ganapathi Raman, R.
Sivaprakash, P.
Viji, A.
Cho, Shin Hum
Kim, Ikhyun
author_sort Velmurugan, G.
collection PubMed
description This work reports on the photocatalytic activity of tin oxide (SnO(2))-doped magnesium (Mg) and fluorine (F) nanoparticles for methyl orange and safranin dye degradation under sunlight irradiation. Nanocatalysis-induced dye degradation was examined using UV–visible spectroscopy and a pseudo-first-order kinetics model. The results indicate that the prepared nanoparticles exhibit superior photocatalytic activity, and the degradation of methyl orange (MO) dye is approximately 82%. In contrast, the degradation of safranin dye is 96% in the same time interval of 105 min. The calculated crystallite size of the SnO(2)–Mg–F nanocomposite is 29.5 nm, which respects the particle size found in the DLS analysis with a tetragonal structure and spherical morphology affirmed. The optical characteristics were assessed, and their respective bandgap energies were determined to be 3.6 eV. The influence of F in Mg and SnO(2) is recognized with the XRD and FT-IR spectra of the prepared particles.
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spelling pubmed-104899312023-09-09 Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation Velmurugan, G. Ganapathi Raman, R. Sivaprakash, P. Viji, A. Cho, Shin Hum Kim, Ikhyun Nanomaterials (Basel) Article This work reports on the photocatalytic activity of tin oxide (SnO(2))-doped magnesium (Mg) and fluorine (F) nanoparticles for methyl orange and safranin dye degradation under sunlight irradiation. Nanocatalysis-induced dye degradation was examined using UV–visible spectroscopy and a pseudo-first-order kinetics model. The results indicate that the prepared nanoparticles exhibit superior photocatalytic activity, and the degradation of methyl orange (MO) dye is approximately 82%. In contrast, the degradation of safranin dye is 96% in the same time interval of 105 min. The calculated crystallite size of the SnO(2)–Mg–F nanocomposite is 29.5 nm, which respects the particle size found in the DLS analysis with a tetragonal structure and spherical morphology affirmed. The optical characteristics were assessed, and their respective bandgap energies were determined to be 3.6 eV. The influence of F in Mg and SnO(2) is recognized with the XRD and FT-IR spectra of the prepared particles. MDPI 2023-09-04 /pmc/articles/PMC10489931/ /pubmed/37687002 http://dx.doi.org/10.3390/nano13172494 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Velmurugan, G.
Ganapathi Raman, R.
Sivaprakash, P.
Viji, A.
Cho, Shin Hum
Kim, Ikhyun
Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title_full Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title_fullStr Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title_full_unstemmed Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title_short Functionalization of Fluorine on the Surface of SnO(2)–Mg Nanocomposite as an Efficient Photocatalyst for Toxic Dye Degradation
title_sort functionalization of fluorine on the surface of sno(2)–mg nanocomposite as an efficient photocatalyst for toxic dye degradation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10489931/
https://www.ncbi.nlm.nih.gov/pubmed/37687002
http://dx.doi.org/10.3390/nano13172494
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