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Exploring the Effects of Various Two-Dimensional Supporting Materials on the Water Electrolysis of Co-Mo Sulfide/Oxide Heterostructure

In this study, various two-dimensional (2D) materials were used as supporting materials for the bimetallic Co and Mo sulfide/oxide (CMSO) heterostructure. The water electrolysis activity of CMSO supported on reduced graphene oxide (rGO), graphite carbon nitride (gC(3)N(4)), and siloxene (SiSh) was b...

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Detalles Bibliográficos
Autores principales: Huynh, Ngoc-Diem, Choi, Won Mook, Hur, Seung Hyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10490037/
https://www.ncbi.nlm.nih.gov/pubmed/37686972
http://dx.doi.org/10.3390/nano13172463
Descripción
Sumario:In this study, various two-dimensional (2D) materials were used as supporting materials for the bimetallic Co and Mo sulfide/oxide (CMSO) heterostructure. The water electrolysis activity of CMSO supported on reduced graphene oxide (rGO), graphite carbon nitride (gC(3)N(4)), and siloxene (SiSh) was better than that of pristine CMSO. In particular, rGO-supported CMSO (CMSO@rGO) exhibited a large surface area and a low interface charge-transfer resistance, leading to a low overpotential and a Tafel slope of 259 mV (10 mA/cm(2)) and 85 mV/dec, respectively, with excellent long-term stability over 40 h of continuous operation in the oxygen evolution reaction.