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Stereospecific synthesis of silicon-stereogenic optically active silylboranes and general synthesis of chiral silyl Anions

Silicon-stereogenic optically active silylboranes could potentially allow the formation of chiral silyl nucleophiles as well as the synthesis of various chiral silicon compounds. However, the synthesis of such silicon-stereogenic silylboranes has not been achieved so far. Here, we report the synthes...

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Detalles Bibliográficos
Autores principales: Wang, Xihong, Feng, Chi, Jiang, Julong, Maeda, Satoshi, Kubota, Koji, Ito, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10492825/
https://www.ncbi.nlm.nih.gov/pubmed/37689789
http://dx.doi.org/10.1038/s41467-023-41113-z