Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds

Ether derivatives are widespread as essential building blocks in various drugs, natural products, agrochemicals, and materials. Modern economy requires developing green strategies with improved efficiency and reduction of waste. Due to its atom and step-economy, the cross-dehydrogenative coupling (C...

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Autores principales: Yu, Hui, Xu, Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10494247/
https://www.ncbi.nlm.nih.gov/pubmed/37701303
http://dx.doi.org/10.3762/bjoc.19.94
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author Yu, Hui
Xu, Feng
author_facet Yu, Hui
Xu, Feng
author_sort Yu, Hui
collection PubMed
description Ether derivatives are widespread as essential building blocks in various drugs, natural products, agrochemicals, and materials. Modern economy requires developing green strategies with improved efficiency and reduction of waste. Due to its atom and step-economy, the cross-dehydrogenative coupling (CDC) reaction has become a major strategy for ether functionalization. This review covers C–H/C–H cross-coupling reactions of ether derivatives with various C–H bond substrates via non-noble metal catalysts (Fe, Cu, Co, Mn, Ni, Zn, Y, Sc, In, Ag). We discuss advances achieved in these CDC reactions and hope to attract interest in developing novel methodologies in this field of organic chemistry.
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spelling pubmed-104942472023-09-12 Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds Yu, Hui Xu, Feng Beilstein J Org Chem Review Ether derivatives are widespread as essential building blocks in various drugs, natural products, agrochemicals, and materials. Modern economy requires developing green strategies with improved efficiency and reduction of waste. Due to its atom and step-economy, the cross-dehydrogenative coupling (CDC) reaction has become a major strategy for ether functionalization. This review covers C–H/C–H cross-coupling reactions of ether derivatives with various C–H bond substrates via non-noble metal catalysts (Fe, Cu, Co, Mn, Ni, Zn, Y, Sc, In, Ag). We discuss advances achieved in these CDC reactions and hope to attract interest in developing novel methodologies in this field of organic chemistry. Beilstein-Institut 2023-09-06 /pmc/articles/PMC10494247/ /pubmed/37701303 http://dx.doi.org/10.3762/bjoc.19.94 Text en Copyright © 2023, Yu and Xu https://creativecommons.org/licenses/by/4.0/This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.
spellingShingle Review
Yu, Hui
Xu, Feng
Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title_full Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title_fullStr Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title_full_unstemmed Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title_short Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
title_sort non-noble metal-catalyzed cross-dehydrogenation coupling (cdc) involving ether α-c(sp(3))–h to construct c–c bonds
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10494247/
https://www.ncbi.nlm.nih.gov/pubmed/37701303
http://dx.doi.org/10.3762/bjoc.19.94
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